The Triplet State
£51.99
- Author: A. B. Zahlan
- Date Published: January 2010
- availability: Available
- format: Paperback
- isbn: 9780521126502
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Originally published in 1967, this volume contains the proceedings of the first international conference held to discuss the triplet state and the various physical phenomena known to be associated with molecules having orbital electrons with parallel spins, and techniques for their investigation. A number of results and ideas in the field of magnetic resonance and phosphorescence of the triplet state are reported for the first time. The topics covered are spin-orbit coupling, intersystem crossing, magnetic resonance, magnetic interactions, photochemistry, radiationless transitions, triplet excitons, delayed fluorescence, phosphorescence and the triplet state related to biology. This volume brought together knowledge concerning the triplet state and defined the problems in need of solution. The review nature of the plenary papers and the good coverage of the volume as a whole made it a basic reference book on the subject, which is still of relevance today.
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×Product details
- Date Published: January 2010
- format: Paperback
- isbn: 9780521126502
- length: 564 pages
- dimensions: 229 x 152 x 32 mm
- weight: 0.82kg
- availability: Available
Table of Contents
Preface
List of participants
Part I. Spin-orbit Coupling and Intersystem Crossing:
1. Spin-orbit interactions in organic molecules
2. Singlet-triplet transitions in organic molecules
3. Triplet decay and intersystem crossing in aromatic hydrocarbons
4. Statistical aspects of resonance energy transfer
Discussion
Part II. Magnetic Resonance and Magnetic Interactions:
5. Magnetic resonance spectra of organic molecules in triplet states in single crystals
6. Magnetic interactions related to phosphorescence
7. ESR investigations of naphthalene-d8:Naphthalene-h8 mixed crystals
8. Biradicals and polyradicals in the nitroxide series
9. Changes induced in the phosphorescent radiation of aromatic molecules by paramagnetic resonance in their metastable triplet states
10. Paramagnetic resonance of the triplet state of tetramethylpyrazine
11. On magnetic dipole contributions to the intrinsic S0 = T1 transition in simple aromatics
Discussion
Part III. Photochemistry:
12. The kinetics of energy transfer from the triplet state in rigid solutions
13. Triplet states in gas-phase photochemistry
14. Biphotonic photochemistry, involving the triplet state: polarisation of the effective T-T transition and solvent effects
15. Direct and sensitised photo-oxidation of aromatic hydrocarbons in boric acid glass
Discussion
Part IV. Radiationless Transitions:
16. Radiationless transitions in gaseous benzene
17. Low-lying excited triplet states and intersystem crossing in aromatic hydrocarbons
18. De-excitation rates of triplet states in condensed media
19. Lifetimes of the triplet state of aromatic hydrocarbons in the vapour phase
Discussion
Part V. Triplet Excitons:
20. Some comments on the properties of triplet excitons in molecular crystals
21. Exact treatment of coherent and incoherent triplet exciton migration
22. Magnetic susceptibility of a system of triplet excitons: Würster's Blue Perchlorate
23. A study of triplet excitons in anthracene crystals under laser excitation
24. The electronic states in crystaline anthracene
Discussion
Part VI. Delayed Fluorescent and Phosphorescence:
25. Delayed fluorescence of solutions
26. The kinetics of the excited states of anthracene and phenanthrene vapor
27. Optical investigations of the triplet states of naphthalene in different crystalline environments
28. Excitation of the triplet states of organic molecules
29. The delayed luminescence and triplet quantum yields of pyrene solutions
30. Triplet state studies of some polyphenyls in rigid glasses
31. Decay time of delayed fluorescence of anthracene as a function of temperature (2–30ºK)
32. Energy transfer between benzene and biacetyl and the lifetime of triplet benzene in the gas phase
33. Charge transfer triplet state of molecular complexes. 34. Flash-photolytic detection of triplet acridine formed by energy transfer from biacetyl
35. Extinction coefficients of triplet-triplet transitions between 3000 and 8800 A in anthracene
36. Anthracene triplet-triplet annihilation rate constant
Discussion
Part VII. Triplet State Related to Biology:
37. ESR and optical studies of some triplet states of biological interest
38. The triplet state of DNA
39. Some characteristics of the triplet states of the nucleic bases
Discussion
Indexes.
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